β-Boron or β-silicon effect enables a regioselective Ni-catalyzed hydrocyanation of internal alkynes
Zhi-Hao Chen, Shuang Lin, Xinman Kang, Jiawu Huang et autres
An Earth-abundant nickel-catalysed regioselective hydrocyanation of propargylic B(MIDA) or silane substrates with AIBN (2,2′-azobis(2-methylpropionitrile)) as a low-toxicity H–CN source is reported.
cn (code pays fourni par la source)