Zhengyuan Gao

Potential Ecological Risks of the Novel Alternative Plasticizer Di(isononyl)cyclohexane-1,2-Dicarboxylate via Metabolic Toxification in Earthworms

Xiuli Fan, Chenggang Gu, Zhengyuan Gao, Zunyao Wang et autres

Abstract As legislative regulations on traditional plasticizers have been tightened globally, diisononyl cyclohexane-1,2-dicarboxylate (DINCH) gains widespread use owing to its environmental safety claims. Nevertheless, the emerging toxicological evidence raises concerns about its health and ecological risks. In soil earthworms, the dynamic bioaccumulation, …

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Microbial-Plant Synergy Underpins the Mitigation of Atrazine Phytotoxicity in Soybean by a Multifunctional Bacterial Seed Coating

Xin Wen, Yuhao Fu, Leilei Xiang, Jean Damascene Harindintwali et autres

Residual herbicides from intensive maize cultivation, particularly atrazine, constrain the soybean establishment in rotation or intercropping systems. To address this, we developed a multifunctional seed coating incorporating a synergistic microbial consortium containing the atrazine-degrading Paenarthrobacter sp. AT5 and the plant growth-promoting Arthrobacter …

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A Metallic Element‐Free Halide‐Ion Battery Enabled by Dual‐halide Regulation in a Hydrogel Electrolyte

Zhiyang Xue, Zhengyuan Gao, Kangjie Xu, Fenglin Yu et autres

Reducing the reliance on metal minerals in rechargeable batteries is an important step toward sustainable energy storage. Although aqueous halogen redox systems are attractive due to their high redox potentials and intrinsic safety, most reported configurations still depend on concentrated metal salt …

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Computational mapping of CYP450 metabolism for Benzotriazole UV absorbers: Biotransformation pathways, mechanisms and environmental implications demonstrated with UV-P

Lezu Shen, Chenggang Gu, Zhengyuan Gao, Xiuli Fan et autres

Benzotriazole UV stabilizers (BT-UVs) are an emerging class of organic pollutants notoriously marked for the environmental ubiquity, bioaccumulativity, and toxicological impacts on human health. Metabolic biotransformation via cytochrome P450 represents a key detoxification route, yet the underlying biotransformation mechanisms of BT-UVs remain …

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Heterostructure‐Engineered TiO 2 ‐TiN Electrocatalyst Boosts Bidirectional Sulfur Redox Kinetics in Magnesium–Sulfur Batteries

Zhengyuan Gao, Huanhuan Xu, Jingwen Tian, Zhiyang Xue et autres

ABSTRACT The sluggish sulfur redox kinetics in magnesium–sulfur (Mg–S) batteries leads to low discharge voltage, poor sulfur utilization, and severe magnesium polysulfides (MgPS) shuttling, limiting their practical energy density. Herein, a heterostructure‐engineered TiO 2 ‐TiN electrocatalyst is rationally constructed and applied to …

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Modulating Electrochemical CO 2 Reduction Pathways via Interfacial Electric Field

Mehdi Salehi, Zhengyuan Gao, Sai Phani Kumar Vangala, Amirhossein Farzi et autres

Abstract Copper (Cu) is a versatile electrocatalyst for the carbon dioxide reduction reaction (CO 2 RR), capable of generating various hydrocarbons. While this versatility is advantageous, controlling product selectivity remains a major challenge. Conventional Cu‐based electrodes often favor ethylene production, limiting the …

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Novel regulatory mechanisms of carboxylesterase by soil organic matter: Correlative insights into enzymatic activation and pollutant degradation via multi–spectral and molecular dynamics approaches

Xiuli Fan, Chenggang Gu, Zhengyuan Gao, Lezu Shen et autres

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Theoretical insights into the binding of mono/di-ethyl phthalates to superoxide dismutase and associated structural changes impairing antioxidant activity: A coupled molecular docking and dynamics simulation approach

Xiuli Fan, Chenggang Gu, Lezu Shen, Zhengyuan Gao et autres

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Active binding mechanism to superoxide dismutase and toxicological implication for environmentally prevalent phthalates and their hydrolytic products: Coupling in vitro bioassay with molecular dynamics simulation

Xiuli Fan, Chenggang Gu, Zhengyuan Gao, Lezu Shen et autres

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Biochemical insights into the biodegradation mechanism of typical sulfonylureas herbicides and association with active enzymes and physiological response of fungal microbes: A multi-omics approach

Zhengyuan Gao, Chenggang Gu, Xiuli Fan, Lezu Shen et autres

The extensive use of sulfonylurea herbicides has raised major concerns regarding their long-term soil residues and agroecological risks despite their role in agricultural protection. Microbial degradation is an important approach to remove sulfonylureas, whereas understanding the associated biodegradation mechanisms, enzymes, and physiological …

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Biochemical Insights into the Biodegradation Mechanism of Typical Sulfonylureas Herbicides and Association with Active Enzymes and Physiological Response of Fungal Microbes: A Multi-Omics Approach

Zhengyuan Gao, Chenggang Gu, Xiuli Fan, Lezu Shen et autres

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Efficient integration of carbon dioxide reduction and 5-hydroxymethylfurfural oxidation at high current density

Roger Lin, Haoyan Yang, Hanyu Zheng, Mahdi Salehi et autres

Combining cathodic CO 2 RR on Sn (green), Cu (blue), and Ag (grey) on carbon paper, or Cu (purple), and Ag (brown) on PTFE with anodic HMFOR on NiP in a flow cell at 100 mA cm −2 improves energy efficiencies while …

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