Clément Chauvier

CCDC 2536933: Experimental Crystal Structure Determination

Salem Ba Sowid, Clément Chauvier, Dimitri Mercier, François Ribot et autres

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, …

CCDC 2536932: Experimental Crystal Structure Determination

Salem Ba Sowid, Clément Chauvier, Dimitri Mercier, François Ribot et autres

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, …

CCDC 2552047: Experimental Crystal Structure Determination

Lamine Saadi, Clément Chauvier

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, …

Author response for "Controlled Au(I)-Mediated Remodeling of NHC Ligand Shells on Gold Nanoparticles Using Bis-NHC–Au(I) Complexes as Exchange Precursors"

Salem Ba Sowid, Clément Chauvier, Dimitri Mercier, Francois Ribot et autres

Synthesis of Arylsilanes by Catalytic Silylation of C(sp 2 )─X Bonds: A Review From the Silicon Perspective

Baptiste Neil, Clément Chauvier

ABSTRACT Arylsilanes constitute an important class of organosilicon compounds with widespread applications in organic synthesis and materials science. Over the past two decades, a range of catalytic synthetic protocols have been developed to access such aromatic organosilanes with increased generality, allowing to …

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Catalytic Alkoxysilylation of (Hetero)Aryl Bromides with tert-Butyl Alkoxysilyldiazenes

Lamine Saadi, Clément Chauvier

Aryl(alkoxy)silanes are valuable building blocks in organic synthesis and materials science, yet their preparation often relies on stoichiometric organometallic reagents or transition metal-catalyzed methods. Herein, we report a catalytic and transition metal-free alkoxysilylation of (hetero)aryl bromides using tert -butyl-substituted alkoxysilyldiazenes ( t …

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4.4.48 Silyldiazenes

Baptiste Neil, Clément Chauvier

Abstract This review describes the synthesis of silyldiazenes, a class of azo compounds derived from diazene (diimide, H—N=N—H), wherein at least one of the two hydrogen atoms is substituted by a silyl group. The discussion covers the two primary subclasses of isolable …

Knowledge Updates 2026/1

J. M. Campagne, J. J. Li, M. Oestreich, S. Z. Zard et autres

Catalytic alkoxysilylation of (hetero)aryl bromides with tert -butyl alkoxysilyldiazenes

Lamine Saadi, Clément Chauvier

The first catalytic and transition metal-free alkoxysilylation of (hetero)aryl bromides is presented using N-tert -butyl- N ′-(alkoxysilyl)diazenes as silylating reagents and sodium tert -butoxide as a catalytic initiator.

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Controlled Au( i )-mediated remodeling of NHC ligand shells on gold nanoparticles using bis-NHC–Au( i ) complexes as exchange precursors

Salem Ba Sowid, Clément Chauvier, Dimitri Mercier, Francois Ribot et autres

Bis-NHC–Au(I) complexes mediate ligand exchange reaction on NHC–AuNPs.

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Author response for "Catalytic Alkoxysilylation of C–H bonds with tert-Butyl-Substituted Alkoxysilyldiazenes"

Lamine Saadi, Clément Chauvier

Catalytic Silylation of Alkynyl C(sp)–H Bonds with tert ‐Butyl‐Substituted Silyldiazenes

Yan Zeng, Louis Fensterbank, Clément Chauvier

Abstract The deprotonative silylation of terminal alkynes constitutes one of the most privileged strategies to prepare alkynylsilanes owing to the relatively high acidity of C(sp)–H bonds. While the key deprotonation step is usually mediated by stoichiometric amounts of strong Brønsted bases (e.g., …

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