Hugh J. Sanderson

NMR raw and processed data.zip

Thomas Simler, Disha Bhattacharjee, Harsh Pratap SINGH, Hugh J. Sanderson et autres

NMR data of the new isolated complexes described in this article (raw fid files from a Bruker spectrometer + processed data using Bruker TopSpin 3.6.5)

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README.txt

Thomas Simler, Disha Bhattacharjee, Harsh Pratap SINGH, Hugh J. Sanderson et autres

Description of the attached files

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Replication data for CO2 Reduction by Lanthanum Borohydride Complexes and Hydroboration Reactivity

Thomas Simler, Disha Bhattacharjee, Harsh Pratap SINGH, Hugh J. Sanderson et autres

The files below correspond to the raw experimental data associated with the publication entitled: "CO2 Reduction by Lanthanum Borohydride Complexes and Hydroboration Reactivity". - Published in Inorganic Chemistry (2026). DOI: 10.1021/acs.inorgchem.5c05811 . The following raw experimental data files are included: raw and …

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CO 2 Reduction by Lanthanum Borohydride Complexes and Hydroboration Reactivity

Disha Bhattacharjee, Harsh P. Singh, Hugh J. Sanderson, Grégory Nocton et autres

Although lanthanide borohydride precursors are useful building blocks to access molecular lanthanide complexes, the nucleophilic reactivity of the attached [BH 4 ] − unit has not been thoroughly investigated. We herein report the reaction of [La(Cp ttt ) 2 (BH 4 )] …

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CO2 reduction by lanthanide borohydride complexes and hydroboration reactivity

Disha Bhattacharjee, Harsh P. Singh, Hugh J. Sanderson, Grégory Nocton et autres

Although lanthanide borohydride precursors are useful building blocks to access a variety of molecular lanthanide complexes, the nucleophilic reactivity of the attached [BH 4 ] – unit has not been thoroughly investigated. We herein report the reaction of [La(Cp ttt ) 2 …

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CO2 reduction by lanthanide borohydride complexes and hydroboration reactivity

Hugh J. Sanderson, Grégory Nocton, Thomas Simler

Although lanthanide borohydride precursors are useful building blocks to access a variety of molecular lanthanide complexes, the nucleophilic reactivity of the attached [BH4]– unit has not been thoroughly investigated. We herein report the reaction of [La(Cpttt)2(BH4)] (1, Cpttt = 1,2,4-tris(tert-butyl)cyclopentadienyl) towards CO2, …

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Reversible formation of tetraphenylpentalene, a room temperature stable antiaromatic hydrocarbon

Hugh J. Sanderson, Andreas Helbig, Gabriele I. Kociok-Köhn, Holger Helten et autres

A rare example of a small, easily synthesisable hydrocarbon which can reversibly switch between aromatic and anti-aromatic states without any skeletal or conformational changes is reported.

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Synthesis and Structure of Heavy Alkali Metal Pentalenides

Hugh J. Sanderson, Sumanta Banerjee, Mandeep Kaur, Alan Robert Kennedy et autres

Abstract The solid‐state structures of the first rubidium and caesium pentalenides [Rb(THF)]2[Ph4Pn] and [Cs(THF)]2[Ph4Pn] have been determined by single crystal X‐ray diffraction. Both were found to be polymeric in the solid state through interactions of the cations with the phenyl substituents, in …

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Twinned versus linked organometallics - bimetallic “half-baguette” pentalenide complexes of Rh( i )

Hugh J. Sanderson, Gabriele I. Kociok-Köhn, Claire Louise McMullin, Ulrich Hintermair

Bimetallic “baguette” versions of the popular CpRh(I) “sandwich” complexes have been synthesised with a tetraarylated pentalenide. The factors leading to syn versus anti metallation have been investigated and the scope of ligand substitution is explored.

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Understanding and tuning the electronic structure of pentalenides

Niko A. Jenek, Andreas Helbig, Stuart M. Boyt, Mandeep Kaur et autres

We report the first systematic study of substituent effects on the electronic structure of pentalenides, giving insight into charge distribution, aromaticity and polarisation effects.

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CCDC 2270786: Experimental Crystal Structure Determination

Hugh J. Sanderson, Gabriele I. Kociok-Köhn, Ulrich Hintermair

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, …

CCDC 2270785: Experimental Crystal Structure Determination

Hugh J. Sanderson, Gabriele I. Kociok-Köhn, Ulrich Hintermair

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, …