Claire Louise McMullin

Dialkyl Ethers and Sacrificial Zinc: Oxide Synthons for Calcium tert ‐Butoxide Formation

Kyle G. Pearce, Agustín Morales, Michael S. Hill, Claire Louise McMullin

ABSTRACT The calcium hydride, [(BDI)CaH] 2 (BDI = HC{C(Me)NDipp} 2 , where Dipp = 2,6‐ i‐ Pr 2 C 6 H 3 ), reacts with Zn t ‐Bu 2 to form the monomeric and toluene‐stabilised calcium dialkyl(hydrido)zincate, [(BDI)Ca‐μ‐H‐Zn( t ‐Bu) 2 (η …

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Dialkyl Ethers and Sacrificial Zinc: Oxide Synthons for Calcium tert ‐Butoxide Formation

Kyle G. Pearce, Agustín Morales, Michael S. Hill, Claire Louise McMullin

ABSTRACT The calcium hydride, [(BDI)CaH] 2 (BDI = HC{C(Me)NDipp} 2 , where Dipp = 2,6‐ i‐ Pr 2 C 6 H 3 ), reacts with Zn t ‐Bu 2 to form the monomeric and toluene‐stabilised calcium dialkyl(hydrido)zincate, [(BDI)Ca‐μ‐H‐Zn( t ‐Bu) 2 (η …

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A lead(I) dimer supported by an amidinate ligand

George W. A. Smith, Samuel E. Neale, Claire Louise McMullin, J. Robin Fulton et autres

The lead(I) dimer [Pb( t Bu Am Dipp )] 2 ([ t Bu Am Dipp ] – = [ tBuC{NDipp} 2 ] – , Dipp = 2,6- iPr 2 C 6 H 3 ) was formed as a side product during the …

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Xanthene-to-fluorene skeletal editing via oxygen deletion mediated by boron and aluminium radicals

Emily E. Nahon, Gareth R. Nelmes, Elena Dallerba, Li Feng Lim et autres

Taking oxygen-free chemistry to the next level: the O -deletion reaction of diamidoarylether ligands coordinated to boron or aluminium is presented, affording 4,5-diaminofluorene compounds on a gram scale.

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A strontium alumanyl

Kyle G. Pearce, Han‐Ying Liu, Claire Louise McMullin, Michael S. Hill

The strontium alumanyl, [(BDI)SrAl(SiN Dipp )], has been prepared from [(BDI)Sr(BPh 4 )] and [(SiN Dipp )AlK] 2 .

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Challenges in ALD precursor design: mechanism of intramolecular C–H activation by internal deprotonation of tin( ii ) precursors

Joe C. Goodall, Agustín Morales, Samuel H. Foote, Oliver W. S. Clark et autres

The thermal decomposition of homoleptic bis( N -alkyl-substituted-silylamido)stannylenes [Sn{NR(TMS)} 2 ] [R = i Pr, Cy, t Bu, Ad (Ad = 1-adamantyl), CPh 3 ] results in the intramolecular C–H activation by deprotonation and formation of tin( iv ) spiro products and …

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Reductive Deamination of a Diaminogermylene Promoted by an Aluminyl Anion: Isolation of Ge(I), Ge(0) and Ge(‐I) Products

George W. A. Smith, Andrea O’Reilly, Claire Louise McMullin, J. Robin Fulton et autres

Abstract The reaction of the potassium aluminyl K[Al(NON)] ([NON] 2− = [O(SiMe 2 NDipp) 2 ] 2− , Dipp = 2,6‐ i Pr 2 C 6 H 3 ) with the diaminogermylene Ge[N(SiMe 3 ) 2 ] 2 afforded [K(C 6 H …

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Reductive Deamination of a Diaminogermylene Promoted by an Aluminyl Anion: Isolation of Ge(I), Ge(0) and Ge(‐I) Products

George W. A. Smith, Andrea O’Reilly, Claire Louise McMullin, J. Robin Fulton et autres

Abstract The reaction of the potassium aluminyl K[Al(NON)] ([NON] 2− = [O(SiMe 2 NDipp) 2 ] 2− , Dipp = 2,6‐ i Pr 2 C 6 H 3 ) with the diaminogermylene Ge[N(SiMe 3 ) 2 ] 2 afforded [K(C 6 H …

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Arene Activation by Calcium Hydride/Zinc Amide Equilibration

Kyle G. Pearce, Michael S. Hill, Mary F. Mahon, Claire Louise McMullin

High Resolution Image Download MS PowerPoint Slide The β-diketiminato calcium hydride, [(BDI)CaH] 2 (BDI = HC{(Me)CNDipp} 2, where Dipp = 2,6- i -Pr 2 C 6 H 3 ), reacts with [Zn{N(SiMe 3 ) 2 } 2 ] and [Zn(TMP) 2 ] …

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An Alumanyl Test Case of Group 1 Redox Interchange

Kyle G. Pearce, Michael S. Hill, Claire Louise McMullin

Abstract Rationalized by a thermochemical evaluation using both theoretical density functional theory (DFT) and empirical data, we show that the arene‐encapsulated M+ cations of the group 1 alumanyls, [{SiNDipp}AlM]2 ({SiNDipp} = {CH2SiMe2N(Dipp)}2; Dipp = 2,6‐i‐Pr2C6H3); M = Li, Na, K, Rb, Cs] …

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Author response for "Enhancing the Nucleophilicity of Aluminyl Anions: Targeting Selective C–H Activation"

Fabian Kallmeier, Gareth R. Nelmes, Claire Louise McMullin, Alison Jeanine Edwards et autres

Author response for "C=O Methylenation mediated by organo-alkali metal reagents: metal identity and ligand effects"

Yang Xiao, Nathan Davison, Paul Gordon Waddell, Roly J. Armstrong et autres