Photoredox/Nickel-Catalyzed Decarboxylative Monofluoromethylation of β-Boryl NHPI Esters via Radical 1,2-Boron Migration
Shuang Lin, Yifan Yang, Qingjiang Li, Shi‐Liang Huang et autres
A photoredox/nickel dual-catalyzed decarboxylative monofluoromethylation of β-boryl NHPI esters has been developed. The reaction proceeds through a radical 1,2-boron shift cascade, enabling the efficient conversion of β-boryl radicals into carbon radicals for subsequent SH2 cross-coupling with a monofluoromethyl radical. This method provides …
tw, cn (code pays fourni par la source)
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Organic Letters