Rathnayake Mudiyanselage Kumuditha Anjala Rathnayake

X-Ray Absorption Spectroscopy Study of Ni-Hexahydroxytriphenylene (HHTP) MOF Catalyst for Liquid Organic Hydrogen Carrier (LOHC) Systems

Rathnayake Mudiyanselage Kumuditha Anjala Rathnayake, Shivam Singh

The shift to green energy highlights Liquid Organic Hydrogen Carrier (LOHC) systems for hydrogen storage, leveraging existing fuel infrastructure. Conventional storage methods, like compression or cryogenics, demand high pressure and low temperatures, making them energy-intensive. LOHC systems chemically bind hydrogen to liquid …

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Chlorination and oxygenation of carbon electrodes for covalent attachment of thiol-terminated molecules

Xin Zheng, Igor L. Bolotin, Beria Tanriover, Rathnayake Mudiyanselage Kumuditha Anjala Rathnayake et autres

This study reports covalent edge plane chlorination of carbon electrodes and their subsequent functionalization with thiol-containing redox-active molecules. Specifically, the reactivity of edge C-H groups on glassy carbon (GC) and carbon powder (CP) electrodes with chlorinating reagents, iodine monochloride and iron(III) chloride, …

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Operando X-Ray Absorption Spectroscopy Investigation of Molybdenum (IV) Oxo Benzene 1,2 Dithiolate [MoIV O(bdt)2] 2- Electrocatalyst Toward Oxygen Atom Transfer Reaction

Rathnayake Mudiyanselage Kumuditha Anjala Rathnayake, Jordi Cabana

Electrocatalytic Oxygen Atom Transfer (E-OAT) reactions are vital in chemical manufacturing, notably in fields such as pharmaceuticals. Inspired by the efficiency of Molybdoenzymes in oxygen atom transfer within biological systems, various Molybdenum compounds have been synthesized to understand chemical oxygen atom transfer. …