Yang Zhang

Precise Measurement of $^{216}$Po Half-life with Exact Parent-daughter Pairing in PandaX-4T

PandaX Collaboration, Chenxiang Li, Zihao Bo, Wei Chen et autres

We report a precise measurement of $^{216}\rm Po$ half-life using the PandaX-4T liquid xenon time projection chamber (TPC). $^{220}\rm Rn $, emanating from a $^{228}\rm Th $ calibration source, is injected to the detector and undergoes successive $α$ decays, first to $^{216}\rm …

Functionalized Hydrocarbon Belts: Synthesis, Structure and Properties

Yi Peng, Shuo Tong, Yang Zhang, Mei‐Xiang Wang

Abstract Hydrocarbon belts have drawn great attention because of their unique structures and tantalizing properties. Although a few belts and heteroatom‐doped analogs have been synthesized, belt molecules containing non‐hexagonal rings remain rare. Herein we report the construction and application of unprecedented zigzag‐type …

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Functionalized Hydrocarbon Belts: Synthesis, Structure and Properties

Yi Peng, Shuo Tong, Yang Zhang, Mei‐Xiang Wang

Abstract Hydrocarbon belts have drawn great attention because of their unique structures and tantalizing properties. Although a few belts and heteroatom‐doped analogs have been synthesized, belt molecules containing non‐hexagonal rings remain rare. Herein we report the construction and application of unprecedented zigzag‐type …

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Synthesis and Structure of Functionalized Zigzag Hydrocarbon Belts

Yang Zhang, Shuo Tong, Mei‐Xiang Wang

Abstract Described in this paper are the synthesis and structure of novel and edge‐functionalized zigzag hydrocarbon belts. A stepwise “fjord‐stitching” strategy featuring repetitive intramolecular acylation reactions of a resorcin[4]arene derivative as the key steps afforded a biscarbonyl‐functionalized octahydrobelt[8]arene product. Facile ketone reduction …

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Synthesis and Structure of Functionalized Zigzag Hydrocarbon Belts

Yang Zhang, Shuo Tong, Mei‐Xiang Wang

Abstract Described in this paper are the synthesis and structure of novel and edge‐functionalized zigzag hydrocarbon belts. A stepwise “fjord‐stitching” strategy featuring repetitive intramolecular acylation reactions of a resorcin[4]arene derivative as the key steps afforded a biscarbonyl‐functionalized octahydrobelt[8]arene product. Facile ketone reduction …

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An Octacationic [2]Catenane Formed by Oxime Condensation: A Bistable Molecular Switch

Cai‐Yun Wang, Guangcheng Wu, Jiaqi Zhu, Tianyu Jiao et autres

Abstract Oxime condensation as well as template‐directed synthesis based on radical‐pairing interactions were used in the synthesis of an octacationic [2]catenane in 20 % yield. The [2]catenane consists of two identical mechanically interlocked tetracationic macrocyclic components. Each of the ring components contains …

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Coulombic-enhanced hetero radical pairing interactions

Xujun Zheng, Yang Zhang, Ning Cao, Xin Li et autres

Abstract Spin–spin interactions between two identical aromatic radicals have been studied extensively and utilized to establish supramolecular recognition. Here we report that spin-pairing interactions could also take place between two different π-electron radicals, namely a bipyridinium radical cation (BPY+•) and a naphthalene-1,8:4,5-bis(dicarboximide) …

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Dynamic Systems : Enzymatic Synthesis, Exchange Reactions and Applications in Materials Science

Yang Zhang

This thesis is divided into three parts, revolving around the developments of dynamic systems utilized in dynamic kinetic resolution (DKR) and constitutional dynamic chemistry (CDC). The first section gives an introduction to constitutional dynamics, the core concept of this thesis. Constitutional dynamics …

Synthesis and Supramolecular Structure of 4,4',6,6'-Tetrachloro-2,2'- [(decane-1,10-diyldioxy)bis(nitrilomethylidyne)]diphenol

Wen‐Kui Dong, Xiang Li, Junjiang Wu, Yang Zhang et autres

Salen-type compound and its derivatives have played a significant role in the development of the coordination chemistry as they are one of the most important mixed-donor ligands in the modern coordination chemistry and these compounds have caused growing concern because of their …

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Crystal structure of a new oximato-bridged one-dimension(1D) chain-like copper complex polymer {[Cu4(dmg)2(Hdmg)2(H2dmg)2(H2O)2](ClO4)2}∞

Xuanwen Liu, Sheng Chu, Xiaoqing Wang, Yang Zhang et autres

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