Tsubasa Mimuro

Low‐Viscosity Concentrated Lithium Chloride Solution with Unsymmetrical Ditopic Receptors in Organic Solvents

Tsubasa Mimuro, Manabu Hirasawa, Shinichi Kondo

Ditopic receptors with different terminal substituents on urea moieties linked with ether groups are prepared, and the solubilization of high‐concentration LiCl by the receptors in acetonitrile is evaluated. The unsymmetrical receptors have higher solubility than the corresponding symmetrical receptors, and the complex …

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Stable and highly LiCl concentrated electrolyte with In-situ synthesis of anion receptor

Manabu Hirasawa, Akihiko Yoshida, Akihiro Orita, Tsubasa Mimuro et autres

Abstract A concentrated lithium salt solution is widely used as an electrolyte of lithium-ion batteries. We have previously reported that simple and flexible ditopic receptors bearing anion and cation recognition sites forms LiCl complex resulting in the highly concentrated solution in acetonitrile. …

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Solid–liquid extraction of lithium chloride with a simple and flexible heteroditopic receptor

Tsubasa Mimuro, Seiichi Yoshino, Manabu Hirasawa, Shinichi Kondo

Abstract The global demand for lithium has surged in recent years due to its wide applications in industry and medicine. We have achieved selective solid–liquid extraction of LiCl using a heteroditopic receptor with an ether linker as a cation recognition site and …

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Structure of Ion Pair Receptor Combined with Li+Cl– in Concentrated Acetonitrile Solutions Studied by Neutron Diffraction with 6Li/7Li Isotopic Substitution Method

Yasuo Kameda, Tsubasa Mimuro, Shinichi Kondo, Takashi Honda et autres

Neutron diffraction measurements with the 6 Li/ 7 Li isotopic substitution method have been carried out to obtain direct structural information on the ion pair receptor, C 16 H 34 O 4 N 4, combined with Li + Cl – ion pair …

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Highly concentrated solution of lithium chloride in organic solvents with heteroditopic receptors

Shinichi Kondo, Tsubasa Mimuro, Akihiko Yoshida, Manabu Hirasawa

Abstract The solubilization and selective extraction of lithium salts, in particular lithium chloride, in organic solvents have recently attracted attention due to the application in industry. A heteroditopic receptor 1b, which has ether oxygens and 2 urea moieties as cation and anion …

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Unlocking the Use of LiCl as an Inexpensive Salt for Lithium-Ion Batteries with a Novel Anion Receptor

Manabu Hirasawa, Akihiro Orita, Tsubasa Mimuro, Shinichi Kondo

Lithium chloride (LiCl) is an inexpensive and environmentally friendly salt abundant in the ocean. However, the insolubility of LiCl in conventional electrolyte solvents prevents the practical use of LiCl for lithium-ion batteries. Here, we report a novel method to increase the solubility …

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Highly soluble bisurea derivatives for anion recognition

Tsubasa Mimuro, Akihiko Yoshida, Kazuyuki Kamo, Manabu Hirasawa et autres

, MeCN, 2-butanone, toluene, and THF. Although the anion recognition abilities of receptors 2 and 3 were lower than those of receptors 1, the greatly improved solubilities of receptors 2 and 3 allow the association of anions under more concentrated conditions for …

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Unlocking the Use of LiCl as an Inexpensive Salt for Lithium-Ion Batteries with a Novel Anion Receptor

Manabu Hirasawa, Akihiro Orita, Tsubasa Mimuro, Shinichi Kondo

jp (code pays fourni par la source)

Structure of Ion Pair Receptor Combined with Li+Cl- in Concentrated Acetonitrile Solutions Studied by Neutron Diffraction with 6Li/7Li Isotopic Substitution Method

Yasuo Kameda, Tsubasa Mimuro, Shinichi Kondo, Takashi HONDA et autres