Moises Luzia Pinto

A Green Scalable Method to Prepare Zr Oxide Dicarboxylate Metal–Organic Frameworks

Debanjan Chakraborty, Sanchari Dasgupta, Oleksii Kolmykov, Maria Inês Severino Neves et autres

We report the synthesis of a series of isoreticular hydrophobic microporous zirconium dicarboxylate metal–organic frameworks (MOFs), MIL‐140(Zr)s, under green ambient pressure conditions. Their pore sizes and hydrophilic/hydrophobic balance can be finely adjusted with a view to potential applications. MIL‐140A(Zr) has a pore …

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Removal of Protein-Bound Uremic Toxins by Mixed Matrix Membranes of Cellulose Acetate/Silica/MOF

João M. Santos Dionísio, M Fátima C Guedes da Silva, Ricardo F. S. Pereira, Tânia Frade et autres

Adsorption therapies in hemodialysis have emerged as an innovative approach for removing protein-bound uremic toxins (PBUTs). The present work focuses on the enhancement of the adsorption capacity of hemodialysis membranes through the incorporation of Metal–Organic Frameworks (MOFs). The removal capacity of PBUT …

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Mechanistic Insights Into Nitric Oxide Capture and Release in a Radical‐Scavenging Zinc Ascorbate Metal–Organic Framework

Tia Kristian Tajnšek, Petar Djinović, Matej Huš, Blaž Likozar et autres

Efficient capture and controlled release of nitric oxide (NO) are essential for therapeutic gas delivery. Here, we investigate NO sorption in bioNICS-1, a zinc-based ascorbate metal-organic framework (MOF), and its propionic acid-modified analogue (bioNICS1-actPA). Structural modulation enhances NO uptake and retention, as …

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CAU-10-H: Synthesis Scale-Up at the Pilot Scale, Techno-Economic Analysis, and Application in a Full-Scale Cooling System

Kalle S. Mertin, Abeer Mohtar, Marta Bordonhos, Moises Luzia Pinto et autres

High Resolution Image Download MS PowerPoint Slide Metal–organic frameworks (MOFs) offer a wide range of advantages for modern society. In particular, the growing societal challenges of energy consumption for cooling and water scarcity can be addressed by high-performance MOFs, such as CAU-10-H, …

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Pillared clays, affordable and scalable adsorbent for efficient (V)PSA processes to capture CO2 from cement flue gases

Abeer Mohtar, Tânia Frade, Margarida Jesus, José Marcelo Rodrigues Pereira et autres

Gas-solid adsorption is emerging as a promising technology for carbon capture. Pillared clays (PILCs) were considered as they are physical adsorbents known for their thermal and chemical stability. The synthesis process was optimized for scale-up 50 L reactors where the synthesis time …

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A numerical model for assessing the techno-economic impact of CO2 purity on the whole value chain of Carbon Capture, Transport, Utilization, and Storage

S.A. Nosherwani, Leonardo Azevedo, Moises Luzia Pinto

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CAU-10-H: synthesis scale-up at pilot scale, techno-economic analysis and application in a full-scale cooling system

Kalle S. Mertin, Abeer Al Mohtar, Marta Bordonhos, Moises Luzia Pinto et autres

Metal-organic frameworks (MOFs) offer a wide range of advantages to modern society. In particular, the growing societal challenges of energy consumption for cooling and water scarcity can be addressed by high-performance MOFs, such as CAU-10-H, Al-MIL-160 and MOF-303. To enable the application …

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Spanning the molecular to industrial scale of the adsorption-based separation of CO2/CH4 by MIL-160(Al)

Marta Bordonhos, Afsaneh Marandi, Farid Nouar, Miguel Jorge et autres

The microporous bioderived MIL-160(Al) MOF has been investigated for CO₂/CH₄ separation in the context of biogas upgrading, by complementary experimental and computational studies, from the molecular to the industrial process levels. MIL-160(Al) has been synthesised and shaped into beads using silica, without …

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Customizing porosity and mechanical strength in chitosan-based scaffolds for enhanced bone tissue regeneration

Joana Gonçalves, Moises Luzia Pinto, Paula Ferreira

Chitosan is increasingly employed in bone tissue engineering due to its biocompatibility, biodegradability, and chemical versatility. This study focuses on the design and optimization of chitosan-based scaffolds, emphasizing the influence of key preparation parameters on their structural and mechanical performance. Formulations were …

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Gasotransmitters in Modern Medicine: Promises and Challenges in the Use of Porous Crystalline Carriers

Rosana Vieira Pinto, Moises Luzia Pinto, Christian Serre

Gas therapy using gasotransmitters is of exponential interest due to the growing recognition of gas signaling molecules that can be involved in multiple therapeutic actions. Finding suitable methods for delivering these molecules is crucial, and porous materials, notably metal-organic frameworks (MOFs), have …

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Adsorptive membranes of cellulose acetate CA/SiO2/UiO-66(Zr) for the removal of protein bound uremic toxins

Diogo dos Reis Barradas, Moises Luzia Pinto, Maria Norberta de Pinho, Miguel Minhalma

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Cost Estimation of the Production of MIL-100(Fe) at Industrial Scale from Two Upscaled Sustainable Synthesis Routes

Maria Inês Severino, Cátia M.A.S. Freitas, Vanessa Pimenta, Farid Nouar et autres

Understanding the impact of MOF synthesis conditions on the production cost is vital in order to have a competitive product with a view toward industrial applications. Here, considering the benchmark mesoporous iron(III) trimesate MIL-100(Fe) as a prototypical example, we show that the …

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