2025
article
OpenAlex
Hudson A. Bicalho, Clara V. Diniz, Zoey Davis, Christopher Copeman et autres
While postsynthetic modification (PSM) of metal–organic frameworks (MOFs) through solvent assisted ligand incorporation (SALI) has been extensively studied, particularly in Zr 6 -based MOFs, this PSM approach is largely overlooked in the literature on rare-earth (RE) cluster-based MOFs. In this work, we …
ca
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Accès ouvert
2025
preprint
OpenAlex
Hudson A. Bicalho, Clara V. Diniz, Zoey Davis, Christopher Copeman et autres
While post-synthetic modification (PSM) of metal–organic frameworks (MOFs) through solvent assisted ligand incorporation (SALI) has been extensively studied, particularly in Zr6-based MOFs, this PSM approach is largely overlooked in the literature on rare-earth (RE) cluster-based MOFs. In this work, we explore SALI …
ca
(code pays fourni par la source)
2025
article
OpenAlex
Michelle Pains Duarte, Clara V. Diniz, Hudson A. Bicalho, Rafik Naccache et autres
CAU-28 (CAU = Christian-Albrechts-University) is a zirconium-based metal–organic framework (MOF) that features a bio-renewable linker (furan-2,5-dicarboxylic acid) and can be obtained through a green synthesis. In this work, we report an optimized synthesis of CAU-28, substantially enhancing the yield from 2 to …
ca
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Accès ouvert
2025
preprint
OpenAlex
Hudson A. Bicalho, Isabella Lopez-Delgado, Clara V. Diniz, Zoey Davis et autres
The synthesis of rare-earth cluster-based MOFs is often performed using metal nitrate salts as precursors. In this work, we demonstrate that six other Y(III) precursors can be used as alternatives in the synthesis of Y-CU-45 (CU = Concordia University), yielding reproducible results …
ca, co
(code pays fourni par la source)
Accès ouvert
2025
preprint
OpenAlex
Michelle Pains Duarte, Clara V. Diniz, Hudson A. Bicalho, Rafik Naccache et autres
CAU-28 (CAU = Christian-Albrechts-University) is a zirconium-based metal–organic framework (MOF) that was first dis-covered in 2017. In addition to its biorenewable linker and green synthesis, which uses a microwave for only 2 hours, this MOF also features high thermal and chemical stability, …
ca
(code pays fourni par la source)
2025
article
OpenAlex
Ximena A. Canales Gálvez, Micaela Richezzi, Hudson A. Bicalho, Natalia Labadie et autres
Three new analogues of Tb-UiO-66 with various functional groups (−F, −Br, −NH 2 ) on the terephthalic acid linker of the metal–organic framework (MOF) are synthesized and characterized. The photoluminescent properties of these analogues, as well as Tb-UiO-66 and Tb-UiO-66-(OH) 2, are …
ca, ar
(code pays fourni par la source)
Accès ouvert
2025
article
OpenAlex
Hudson A. Bicalho, Isabella Lopez-Delgado, Clara V. Diniz, Zoey Davis et autres
The synthesis of rare-earth cluster-based MOFs is often performed using metal nitrate salts as precursors. In this work, we demonstrate that six other Y(III) precursors can be used as alternatives in the synthesis of Y-CU-45 (CU = Concordia University), yielding reproducible results …
us, ca, co
(code pays fourni par la source)
2024
paratext
OpenAlex
Hudson A. Bicalho, Christopher Copeman, Helliomar P. Barbosa, P. Rafael Donnarumma et autres
A new series of rare-earth metal–organic frameworks with 6-connected hexanuclear cluster nodes and spn topology are reported. They exhibit photoluminescence spanning the visible and near-infrared regions of the electromagnetic spectrum. More information can be found in the Research Article by A. J. …
ca, de
(code pays fourni par la source)
Accès ouvert
2024
preprint
OpenAlex
Ximena A. Canales Gálvez, Micaela Richezzi, Hudson A. Bicalho, Natalia Labadie et autres
Three new analogues of Tb-UiO-66 with various functional groups (–F, –Br, –NH2) on the terephthalic acid linker of the metal–organic framework (MOF) are synthesized and characterized. The photoluminescent properties of these analogues, as well as Tb-UiO-66 and Tb-UiO-66-(OH)2, are studied and correlated …
ca, ar
(code pays fourni par la source)
Accès ouvert
2024
preprint
OpenAlex
Ximena A. Canales Gálvez, Micaela Richezzi, Hudson A. Bicalho, Natalia Labadie et autres
Three new analogues of Tb-UiO-66 with various functional groups (–F, –Br, –NH2) on the terephthalic acid linker of the metal–organic framework (MOF) are synthesized and characterized. The photoluminescent properties of these analogues, as well as Tb-UiO-66 and Tb-UiO-66-(OH)2, are studied and correlated …
ca, ar
(code pays fourni par la source)
2024
article
OpenAlex
Hudson A. Bicalho, Lavinia A. Trifoi, Victor Quezada‐Novoa, Ashlee J. Howarth
The design and synthesis of luminescent and photoactive metal–organic frameworks (MOFs) are of interest from both a fundamental and application standpoint. Luminescent and photoactive MOFs can be designed to have photophysical properties similar to those of other materials, with the added benefit …
ca
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Accès ouvert
2024
article
OpenAlex
Hudson A. Bicalho, Christopher Copeman, Helliomar P. Barbosa, P. Rafael Donnarumma et autres
In this work, nine new rare-earth metal-organic frameworks (RE-MOFs, where RE=Lu(III), Yb(III), Tm(III), Er(III), Ho(III), Dy(III), Tb(III), Gd(III), and Eu(III)) isostructural to Zr-MOF-808 are synthesized, characterized, and studied regarding their photophysical properties. Materials with high crystallinity and surface area are obtained from …
ca, de
(code pays fourni par la source)