Tomoki Hirohata

Dual‐Functional Polystyrene‐Based Borate Complexes: Recyclable Alkyl Radical Sources and Photodegradable Absorbents

Nami Jimba, Ryosei Ishii, Kazuki Wako, Tomoki Hirohata et autres

Recyclable polymeric materials capable of generating radicals under mild conditions are valuable materials in synthetic chemistry. Herein, we report polystyrene-based copolymers bearing 2,2'-(pyridine-2,6-diyl)diphenol (PDP) moieties that form alkyl borate complexes and release alkyl radicals upon blue-light irradiation. The generated primary and secondary …

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Size-Selective Capture of Fluorocarbon Gases and Storage of Volatile Halogenated Organic Vapors with Low Boiling Points by Molecular-Scale Cavities of Crystalline Pillar[n]quinones

啓佑 和田, Keisuke Wada, 廣畑 智紀, Tomoki Hirohata et autres

ホウ素錯体を担持した高分子の光励起によるアルキルラジカルの生成とその応用

良誠 石井, Ryosei Ishii, 智紀 廣畑, Tomoki Hirohata et autres

Size‐Selective Capture of Fluorocarbon Gases and Storage of Volatile Halogenated Organic Vapors with Low Boiling Points by Molecular‐Scale Cavities of Crystalline Pillar[n]quinones

Shunsuke Ohtani, Katsuto Onishi, Keisuke Wada, Tomoki Hirohata et autres

Abstract Fluorocarbon gases are regarded as one of the largest contributors to serious environmental problems such as ozone‐depletion and global warming, and thus, the development of reclamation technologies is in great demand for reducing emission of such harmful compounds. So far, porous …

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Morphologically Controlled Electrochemical Assembly of Pillar[6]quinone Crystals through the Interaction with Electrolytes

Tomoki Hirohata, Naoki Shida, Elena Villani, Tomoki Ogoshi et autres

Abstract The morphology engineering of porous materials is advantageous for improving their properties and designing the structure of their nanopores. Among the synthetic methods available, electrochemical deposition is one of the most advantageous for shape engineering, because the reaction conditions can be …

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Morphologically Controlled Electrochemical Assembly of Pillar[6]quinone Crystals through the Interaction with Electrolytes

廣畑 智紀, Tomoki Hirohata, 尚毅 信田, Naoki Shida et autres

ホウ素錯体を側鎖に有する高分子の光励起によるアルキルラジカルの生成とその応用

良誠 石井, Ryosei Ishii, 智紀 廣畑, Tomoki Hirohata et autres

Innenrücktitelbild: Site‐Selective Synthesis and Concurrent Immobilization of Imine‐Based Covalent Organic Frameworks on Electrodes Using an Electrogenerated Acid (Angew. Chem. 40/2023)

Tomoki Shirokura, Tomoki Hirohata, Kosuke Sato, Elena Villani et autres

Imine-based covalent organic frameworks (COFs) were successfully formed and immobilized on an electrode surface promoted by electrogenerated acids, as demonstrated by Shinsuke Inagi et al. in their Research Article (e202307343).

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Inside Back Cover: Site‐Selective Synthesis and Concurrent Immobilization of Imine‐Based Covalent Organic Frameworks on Electrodes Using an Electrogenerated Acid (Angew. Chem. Int. Ed. 40/2023)

Tomoki Shirokura, Tomoki Hirohata, Kosuke Sato, Elena Villani et autres

Imine-based covalent organic frameworks (COFs) were successfully formed and immobilized on an electrode surface promoted by electrogenerated acids, as demonstrated by Shinsuke Inagi et al. in their Research Article (e202307343).

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Site‐Selective Synthesis and Concurrent Immobilization of Imine‐Based Covalent Organic Frameworks on Electrodes Using an Electrogenerated Acid

Tomoki Shirokura, Tomoki Hirohata, Kosuke Sato, Elena Villani et autres

Imine-based covalent organic frameworks (COFs) are crystalline porous materials with prospective uses in various devices. However, general bulk synthetic methods usually produce COFs as powders that are insoluble in most of the common organic solvents, arising challenges for the subsequent molding and …

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Site‐Selective Synthesis and Concurrent Immobilization of Imine‐Based Covalent Organic Frameworks on Electrodes Using an Electrogenerated Acid

Tomoki Shirokura, Tomoki Hirohata, Kosuke Sato, Elena Villani et autres

Abstract Imine‐based covalent organic frameworks (COFs) are crystalline porous materials with prospective uses in various devices. However, general bulk synthetic methods usually produce COFs as powders that are insoluble in most of the common organic solvents, arising challenges for the subsequent molding …

jp, us (code pays fourni par la source)

Site-Selective Synthesis and Concurrent Immobilization of Imine-Based Covalent Organic Frameworks on Electrodes Using an Electrogenerated Acid

智基 白倉, Tomoki Shirokura, 廣畑 智紀, Tomoki Hirohata et autres

Imine-based covalent organic frameworks (COFs) are crystalline porous materials with prospective uses in various devices.However, general bulk synthetic methods usually produce COFs as powders that are insoluble in most of the common organic solvents, arising challenges for the subsequent molding and fixing …

jp, us (code pays fourni par la source)