Wen‐Ping Zhang

Electrocatalytic amine dehydrogenation as a green route to nitriles: precise construction of efficient catalysts and mechanism

Long Chen, Wen‐Ping Zhang, Hao Tan, Yuping Zhang et autres

characterization, theoretical calculations, and performance evaluation, we further identify key future research directions, including multi-scale optimization of catalytic systems, electrolyzer design, and techno-economic analysis. This review aims to offer theoretical insights and practical guidance for the development of efficient, stable, and scalable …

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Oxygen Spillover: Revolutionizing Catalytic Performance and Disrupting Mechanistic Paradigms in Sustainable Chemistry

Zhao‐Hua Yin, Wen‐Ping Zhang, Wei Luo, Hong Liu et autres

Oxygen spillover, a dynamic interfacial phenomenon in catalysis, enables the migration of active oxygen species (*O, *OH) across catalyst interfaces, overcoming the limitations of traditional static active sites and establishing a new paradigm for optimizing catalytic performance in sustainable chemistry. This review …

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Enantioselective Si−H Insertion of Arylvinyldiazoesters Promoted by Rhodium(I)/Diene Complexes

Ziyan Li, Jianguo Liu, Wen‐Ping Zhang, Ming‐Hua Xu

Abstract An enantioselective Si−H insertion between α‐arylvinyldiazoesters and silanes has been developed by employing rhodium(I)/chiral diene complex as the catalyst. This protocol offers a catalytic asymmetric approach to various chiral silanes containing α‐arylvinyl functionality at room temperature with good enantiocontrol (89–99% ee). …

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Iridium-Catalyzed Asymmetric Hydrogenation of Exocyclic Ketones, Lactones, and Lactams

Wen‐Ping Zhang, Fuli Tian, Dongmei Yao, Y. Liu et autres

Significance The authors discovered a very efficient iridium-catalyzed process for asymmetric hydrogenation of exocyclic α,β-unsaturated carbonyl compounds using axis-unfixed phosphine oxazoline ligands. Five-membered exocyclic α,β-unsaturated ketones, lactones, and lactams were hydrogenated to generate corresponding α-chiral carbonyl compounds in high conversion and enantioselectivities.