Xiang‐Ting Min

Carboxyl-directed, general α-site-selective deuteration of carboxylic acids by Pd1/CeOx single-atom catalyst

Juan Su, Xiang‐Ting Min, Yike Huang, Xu Fang et autres

Carboxylic acids are ubiquitous structural motifs in bioactive molecules, making their site-selective deuteration a powerful tool for probing biochemical mechanisms and improving the pharmacokinetic properties of drug molecules. Late-stage H/D exchange offers superiority over de novo synthesis from deuterated precursors, but remains …

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Carboxyl-directed, general α-site-selective deuteration of carboxylic acids by Pd1/CeOx single-atom catalyst.

Juan Su, Xiang‐Ting Min, Yike Huang, Xu Fang et autres

surface anchors the carboxylate, while the Pd mediates α-C - H bond activation. This method features a broad substrate scope and excellent site-selectivity, underscoring its generality and establishing a versatile platform for late-stage isotopic labeling of pharmaceuticals and other complex molecules.

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Recent Advances in Zeolite-Based Catalysts for Hydroisomerization of Long-Chain Alkanes

Yuge Jin, Wenxi Li, Juan Wu, Cun Liu et autres

Long-chain n-alkane hydroisomerization is a key catalytic route for upgrading wax-rich, bio-derived, and synthetic hydrocarbon feedstocks into diesel fuels, sustainable aviation fuels, and lubricant base oils with improved low-temperature properties. However, selective hydroisomerization remains challenging because mismatches in the spatial proximity and …

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Atomically proximate FeN4 sites and molybdenum–sulfur clusters for efficient bifunctional oxygen electrocatalysis in rechargeable zinc–air batteries

Zihan Wang, Zongge Li, X H Chen, Hongyun Zhao et autres

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Regio‐ and Site‐Selective Organic Synthesis With Single‐Atom Catalysts

Xin Shang, Boyu Yu, Xiang‐Ting Min, Xiong Su et autres

Organic synthesis underpins the manufacture of pharmaceuticals, agrochemicals, and advanced materials. A key challenge is to selectively transform a specific region or site within a molecule while suppressing competing pathways, as different regio- and site-isomers often show distinct properties and increase separation …

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Regio‐ and Site‐Selective Organic Synthesis With Single‐Atom Catalysts

Xin Shang, Boyu Yu, Xiang‐Ting Min, Xiong Su et autres

ABSTRACT Organic synthesis underpins the manufacture of pharmaceuticals, agrochemicals, and advanced materials. A key challenge is to selectively transform a specific region or site within a molecule while suppressing competing pathways, as different regio‐ and site‐isomers often show distinct properties and increase …

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Strong Metal–Support Interaction in Rh/TiO2 Catalysts for Reductive Deuteration of Quinoline

Wenting Zhang, Xiang‐Ting Min, Botao Qiao

Reductive deuteration of N-heterocycles provides an efficient route to deuterated scaffolds, yet achieving controlled deuterium incorporation in quinoline remains challenging. Herein, we report a high-temperature H2-treated Rh/TiO2 catalyst (Rh/TiO2–H500) that enables efficient reductive deuteration of quinoline using D2O as a deuterium source. …

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Selective Aerobic Oxidation of C–H Bond over C–C Bond on Pd 1 /Mn 2 O 3 Single-Atom Catalysts

Tianbo Li, Qiang Zhang, Yufu Zhong, Xiang‐Ting Min et autres

Aerobic oxidation of the C–H bond is a fundamental transformation in heterogeneous catalysis, yet achieving high selectivity remains challenging because the oxidation products are often more reactive than the starting hydrocarbons. Herein, we demonstrate that a Mn 2 O 3 -supported Pd …

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Supported nanoparticles and single-atom catalysts for the synthesis of deuterated alcohols

Jingjing Tang, Shu-Xian Li, Wen-Xin Zhou, Xiang‐Ting Min et autres

Deuterated alcohols are valuable synthetic targets due to their roles in pharmaceuticals, materials, and mechanistic studies. Conventional homogeneous strategies for their synthesis, while effective, often require expensive ligands and offer limited catalyst recovery. Heterogeneous catalysis, by contrast, provides a robust and recyclable …

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Catalytic Decarbonylation of Aldehydes: Recent Advances and Future Perspectives

Wen‐Xin Zhou, Jing‐Jing Tang, Ming‐Wei Ji, Shuxian Li et autres

This review highlights the expanding role of decarbonylation in modern organic chemistry. Inspired by nature's enzymatic pathways, aldehyde decarbonylation, which enables C−C bond cleavage with the release of carbon monoxide, has emerged as a powerful and versatile transformation in sustainable synthesis, complex …

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Atomically Dispersed Rhodium on TiO2 for Tandem Hydrogenation–H/D Exchange of Cinnamic Acid

Fatima Asif, Shuxian Li, Xiang‐Ting Min, Bin Zhang et autres

An atomically dispersed rhodium on TiO2 catalyst enables a tandem process, combining hydrogenative reduction with α,β-hydrogen–deuterium exchange of cinnamic acid, in which D2O serves as the deuterium source. In contrast with previous reductive deuteration methods that yield only partially labeled 3-phenylpropanoic acids …

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Silanols-stabilized zinc cations in self-pillared pentasil zeolite as an efficient catalyst for direct propane dehydrogenation

Zhaopeng Liu, Jun Zhao, Boyu Yu, Fang Xu et autres

Propane dehydrogenation (PDH) offers a promising route for on-demand propylene production, yet developing cost-effective and durable non-noble metal catalysts remains challenging. Herein, we report a silanol (Si–OH) stabilized Zn catalyst supported on hierarchical self-pillared pentasil (SPP) zeolite, synthesized via the metal-ligand protection …