Trevor P. Latendresse

Lewis Base-Enhanced C–H Bond Functionalization Mediated by a Diiron Imido Complex

Reilly K. Gwinn, Trevor P. Latendresse, Owen N. Beck, Carla Slebodnick et autres

High Resolution Image Download MS PowerPoint Slide Herein, we investigate the effects of ligand design on the nuclearity and reactivity of metal–ligand multiply bonded (MLMB) complexes to access an exclusively bimetallic reaction pathway for C–H bond functionalization. To this end, the diiron …

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An Open-Shell Fe IV Nitrido

Jeewhan Oh, Shao‐Liang Zheng, Kurtis M. Carsch, Trevor P. Latendresse et autres

We report the photogeneration and characterization of an open-shell, terminal iron nitrido ( Em L)Fe(N) using a sterically encumbered dipyrrin ligand environment. The Fe–N distance in the solid-state, zero-field 57 Fe Mössbauer spectrum, and computational analysis are consistent with a triplet electronic …

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High-Spin [FeI3] Cluster Capable of Pnictogen Atom Capture

Trevor P. Latendresse, Nicholas P. Litak, Joy S. Zeng, Shao‐Liang Zheng et autres

Using a new hexanucleating anildophosphine ligand t Bu LH 3 (1,3,5-C 6 H 9 (NHC 6 H 3 –5-F–2-P( t Bu) 2 ) 3 ), the all-monovalent [Fe I 3 ] compound ( t Bu L)Fe 3 ( 1 ) was isolated …

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Synthesis, Characterization, and the Effect of Lewis Bases on the Nuclearity of Iron Alkoxide Complexes

Reilly K. Gwinn, Matthew Williams, Trevor P. Latendresse, Carla Slebodnick et autres

High Resolution Image Download MS PowerPoint Slide Inspired by the potential of alkoxides as weak-field ligands and their ability to bridge, we report herein a series of high-spin iron complexes supported by a bis-alkoxide framework Ph Dbf . A diiron complex [Fe …

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CCDC 1955955: Experimental Crystal Structure Determination

Gabrielle M. Risica, Veacheslav Vieru, Branford O. Wilkins, Trevor P. Latendresse et autres

CCDC 1955962: Experimental Crystal Structure Determination

Gabrielle M. Risica, Veacheslav Vieru, Branford O. Wilkins, Trevor P. Latendresse et autres

CCDC 1955959: Experimental Crystal Structure Determination

Gabrielle M. Risica, Veacheslav Vieru, Branford O. Wilkins, Trevor P. Latendresse et autres

CCDC 1955961: Experimental Crystal Structure Determination

Gabrielle M. Risica, Veacheslav Vieru, Branford O. Wilkins, Trevor P. Latendresse et autres

Axial Elongation of Mononuclear Lanthanide Metallocenophanes: Magnetic Properties of Dysprosium‐ and Terbium‐[1]Ruthenocenophane Complexes

Gabrielle M. Risica, Veacheslav Vieru, Branford O. Wilkins, Trevor P. Latendresse et autres

Abstract We report the first f‐block‐ruthenocenophane complexes 1 (Dy) and 2 (Tb) and provide a comparative discussion of their magnetic structure with respect to earlier reported ferrocenophane analogues. While axial elongation of the rare trigonal‐prismatic geometry stabilizes the magnetic ground state in …

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Axial Elongation of Mononuclear Lanthanide Metallocenophanes: Magnetic Properties of Dysprosium‐ and Terbium‐[1]Ruthenocenophane Complexes

Gabrielle M. Risica, Veacheslav Vieru, Branford O. Wilkins, Trevor P. Latendresse et autres

Abstract We report the first f‐block‐ruthenocenophane complexes 1 (Dy) and 2 (Tb) and provide a comparative discussion of their magnetic structure with respect to earlier reported ferrocenophane analogues. While axial elongation of the rare trigonal‐prismatic geometry stabilizes the magnetic ground state in …

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CCDC 1986810: Experimental Crystal Structure Determination

Trevor P. Latendresse, Veacheslav Vieru, Apoorva Upadhyay, Nattamai S. P. Bhuvanesh et autres

CCDC 1986808: Experimental Crystal Structure Determination

Trevor P. Latendresse, Veacheslav Vieru, Apoorva Upadhyay, Nattamai S. P. Bhuvanesh et autres