Tian‐Lu Sheng

Fulvalene-Bridged Binuclear Complexes: Strongly Antiferromagnetically Coupled Ru III Ru III and Class II–III Mixed-Valence Ru III Ru II

Ying Song, Le Chen, Jin-Hui Fu, Bing-Chang Tan et autres

The binuclear ruthenium–fulvalene complex FvRu 2 (dmoppb) 2 Cl 2 [PF 6 ] 2 ( 1 [PF 6 ] 2; Fv = fulvalene; dmoppb = 1, 2- bis (di(4-methoxyphenyl)-phosphino)butane) was synthesized by an oxidation-induced C–C coupling reaction, and the mixed-valence complex FvRu …

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Excited- and ground-states of chain-like tetranuclear cyanido-pyrazine bridged M2Ru2 (M = Fe, Ru) mixed valence complexes

Xiaolin Liu, Hao Wang, Xintao Wu, Tian‐Lu Sheng

Controlled surface chiral modification of 2D layered MOFs matrices for full-color circularly polarized luminescence

Haitao Li, Tian‐Lu Sheng, Xin‐Tao Wu, Yuehong Wen

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Design, synthesis, and electronic coupling in a series of binuclear Fe-Ru cyanido-bridged compounds

Xiaolin Liu, Hao Wang, Xintao Wu, Tian‐Lu Sheng

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Protonation‐Induced Reversible Switching of Electronic Delocalization in a Linear Ru–Ru–Ru Complex

Jin-Hui Fu, Zhenlin Wu, Ying Jie Song, Beng Jit Tan et autres

Abstract In this work, we report the first example of a molecular switch between electronic delocalization and electronic localization in cyanidometal‐bridged trinuclear mixed‐valence (MV) complex controlled by a protonation reaction. A MV complex with the terminal 2,3‐bis(diphenylphosphino)pyridine (L) ligand which has a …

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Different delocalization ranges of asymmetric isocyanidometal-bridged trinuclear compounds by regulating the metal center and the ligand electron-donating ability

Hao Wang, Xiaolin Liu, Han Liu, Xin‐Tao Wu et autres

A series of asymmetric isocyanidometal-bridged compounds cis-[Cp5(dppe)M(μ-CN)Ru(bpy)2(μ-NC)Ru(dppe)Cpx][PF6]2 (N2+[PF6]2: M = Fe and x = 0, N = 1; M = Fe and x = 1, N = 2; M = Ru and x = 0, N = 3; M = Ru and …

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Recent developments and challenges of molecular design in linear cyanido-bridged multimetallic complexes

Jin-Hui Fu, Beng Jit Tan, Ying Jie Song, Zhenlin Wu et autres

Cyanido-bridged multimetallic complexes have been extensively studied for their potential applications in molecular electronics and spintronics. The design of these complexes involves the strategic placement of metal centers and the use of cyanide bridges to facilitate electron transfer between metal ions. The …

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A T-shaped cyanidometal-bridged tetranuclear Fe 3 Ru complex with oxidation-driven intramolecular charge transfer between metal centres

Hao Wang, Xiaolin Liu, Han Liu, Tian‐Lu Sheng

An oxidation-driven intramolecular charge transfer was observed in a T-shaped cyanidometal-bridged tetranuclear MV complex. The electron communication properties between the cis - and trans -configurations are investigated.

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Controlled Surface Chiral Modification of 2d Layered Mofs Matrices for Full-Color Circularly Polarized Luminescence

Haitao Li, Tian‐Lu Sheng, Xin‐Tao Wu, Yuehong Wen

Chain‐Like Pentanuclear Complexes: Syntheses, Crystal Structures and Long‐Range Electronic Interactions of Cyanido‐Bridged M 2 Ru 3 (M=Fe, Ru)

Xiaolin Liu, Yi Li, Hao Wang, Yuying Yang et autres

Abstract In this work, we report the design and synthesis of two chain‐like pentanuclear cyanido‐bridged complexes trans ‐[Ru(bpy) 2 (μ‐CN) 2 ][ cis ‐Ru(bpy) 2 (μ‐NC)M(dppe)Cp*] 2 [PF 6 ] 4 (M=Fe, 1 4+ ; M=Ru, 2 4+ ) and the electronic …

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Fluorescent Dye‐Based Chiral Crystalline Organic Salt Networks for Circularly Polarized Luminescence

Haitao Li, Qi‐Long Zhu, Tian‐Lu Sheng, Xintao Wu et autres

Abstract A facile and general strategy is developed herein for the construction of circularly polarized luminescence (CPL) materials with simultaneously high fluorescence quantum efficiency (Φ) and large luminescence dissymmetry factor (g lum ). The self‐assembly of fluorescent dye, disodium 4,4′‐bis(2‐sulfonatostyryl)biphenyl (CBS), with …

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Dynamic color‐tunable ultra‐long room temperature phosphorescence polymers with photo‐chromism and water‐stimuli response for multilevel anti‐counterfeiting

Xiao Ma, Tian‐Jiao Ye, Han‐Jiang Yang, Guang‐Kun Ling et autres

Abstract Developing dynamic color‐tunable ultra‐long room temperature phosphorescence (URTP) polymers with afterglow of over 1 s, photo‐chromism, and multi‐stimuli response for practical anti‐counterfeiting and information security applications is attractive but very challenging. Herein, by doping multicolor phosphorescence pyridinium bromide L block or …

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