Extraction of REE(III), U(VI), and Th(IV) from Nitric Acid Solutions with Carbamoylmethylphosphine Oxides Bearing an Additional Phosphoryl Group
Rattachement africain : ru. Niveau de preuve : code pays fourni par la source.
Le résumé fourni par la source
Abstract The extraction of trace amounts of U(VI), Th(IV), and REE(III) from HNO3 solutions with new carbamoylmethylphosphine oxides Ph2P(O)CH2C(O)N(Bu)CH2P(O)Bu2 and Bu2P(O)CH2C(O)N(Bu)CH2P(O)Bu2, containing a phosphoryl group in the amide moiety of the molecule, in dichloroethane has been studied. The stoichiometry of the extracted complexes was determined, and the influence of the extractant structure and aqueous phase composition on the efficiency of U(VI), Th(IV), and REE(III) extraction into the organic phase was examined. It was shown that modification of diphenyl(dialkylcarbamoylmethyl)phosphine oxide by introducing an additional CH2P(O)Bu2 coordinating group via the amide nitrogen atom leads to an increase in the extraction efficiency of REE(III) ions from neutral nitrate solutions and a decrease in their extraction from nitric acid solutions. Replacement of phenyl substituents at the phosphorus atoms in the molecule of diphenyl(dibutylcarbamoylmethyl)phosphine oxide with butyl groups leads to an increase in the extraction efficiency of U(VI) and Th(IV) by the modified compounds from nitric acid solutions and a decrease in the recovery of REE(III) into the organic phase in the presence of an ionic liquid, 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide.
Ce résumé expose les affirmations des auteurs. BNTIC ne l’interprète pas comme une validation indépendante des résultats.
Le contrôle bibliographique ouvert
DOI retrouvé dans Crossref DOI retrouvé ; titre concordant.
- Titre Crossref
- Extraction of REE(III), U(VI), and Th(IV) from Nitric Acid Solutions with Carbamoylmethylphosphine Oxides Bearing an Additional Phosphoryl Group
- Date Crossref
- 21/09/2026
- Éditeur
- Pleiades Publishing Ltd
- Type
- journal-article
Ce recoupement confirme des métadonnées liées au DOI. Il ne confirme ni la méthode ni les conclusions de l’étude, et il ne compte pas comme une seconde source scientifique indépendante.
Où se fait cette recherche
-
Osipyan Institute of Solid State Physics RAS pays non établi dans la noticeStructure de recherche
-
Institute of Microelectronics Technology and High Purity Materials pays non établi dans la noticeStructure de recherche
-
A. N. Nesmeyanov Institute of Organoelement Compounds pays non établi dans la noticeStructure de recherche
-
Kurchatov Institute pays non établi dans la noticeStructure de recherche
-
Osipyan Institute of Solid State Physics of the Russian Academy of Sciences pays non établi dans la noticeStructure de recherche
-
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences pays non établi dans la noticeStructure de recherche
Osipyan Institute of Solid State Physics RAS, Institute of Microelectronics Technology and High Purity Materials et A. N. Nesmeyanov Institute of Organoelement Compounds, avec 3 autres affiliations.
Une affiliation ne permet pas de déduire la nationalité d’un auteur.