Synthesis, crystal structure and Hirshfeld surface analysis of ( Z )-2-({amino[6-phenyl-3-(4-methylphenyl)-1,2,4-triazin-5-yl]methylidene}amino)-6-methoxybenzo[ d ]thiazole-4,7-diyl diacetate

Résumé fourni par la source

The stable conformation of the title molecule, C 29 H 24 N 6 O 5 S, is caused by two intramolecular N—H...N hydrogen bonds producing fused S (5) and S (6) rings. In the crystal, molecules are connected by intermolecular N—H...O interactions along the b -axis direction, forming C (9) chains. Furthermore, there are π–π interactions [centroid–to-centroid distance = 3.8200 (12) Å] between the benzene ring of the p -tolyl group and the 1,2,4-triazine ring in the same direction. As a result, the molecules form ribbons along the b -axis direction,. A Hirshfeld surface analysis was performed, showing the predominance of H...H, O...H/H...O, C...H/H...C and N...H/H...N contacts.

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