Mildly Carbonized Grape Pomace Biochar for Nitrate Removal from Water: Process Optimization by Response Surface Methodology (RSM)

Le résumé fourni par la source

Large volumes of solid waste are produced by the winemaking sector, which could be utilised as adsorbents to retain contaminants, providing a beneficial approach in terms of economic recovery and sustainability. The adsorption of nitrate onto biochar produced from grape pomace has not received enough attention, even though biochar-based materials have been thoroughly studied for water treatment applications. This study aims to fill the knowledge gap by assessing a low-cost mildly carbonized biochar derived from winery residues for nitrate retention and optimising the nitrate retention procedures by comprehensive physicochemical characterisation. The mildly carbonized biochar prepared from grape pomace collected from the Dealu Mare wine region (Romania) was characterized using scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM–EDX), Fourier transform infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET), and thermogravimetric and derivative thermogravimetric (TGA/DTG) analyses. Results revealed a structure enriched with oxygen-containing functional groups that promote nitrate retention through combined physical adsorption and electrostatic interactions. Surface analyses after adsorption confirmed the successful immobilization of nitrate species on the biochar matrix. The adsorption performance was improved by Response Surface Methodology (RSM) method using a Central Composite Design (CCD), studying the influences of the following parameters: solution pH, adsorbent weight, nitrate concentration and time. Among all variables, pH was identified as the dominant factor controlling adsorption efficiency, reflecting the key role of surface charge interactions. The optimized conditions (175 mg/L nitrate, pH 6, 0.3 g adsorbent dosage, and 94 min contact time) resulted in a maximum nitrate removal efficiency (RE) of 86.69%, while the predictive model exhibited excellent accuracy (R2adj = 0.985). The findings demonstrate that mildly carbonized grape pomace biochar can achieve competitive nitrate removal without chemical surface modification, offering a more sustainable and economically attractive alternative to conventionally biochars. The research highlights that selecting feedstock and utilizing intrinsic surface functionality can create efficient nitrate adsorbents from agro-industrial residues.

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