Experimental Study on Water Injection Removal of Ammonium Chloride Particles to Enhance Hydrotreatment Air Cooler Reliability

Le résumé fourni par la source

Hydrotreatment is vital for producing high-quality liquid fuels in petroleum refining and its air coolers are critical components prone to severe corrosion under high-temperature and high-pressure conditions. Ammonium salts from NH3-HCl and NH3-H2S reactions, particularly ammonium chloride precipitated during cooling, readily deposit on tube surfaces. Strong temperature gradients and complex flow conditions may severely affect air cooler inlets and front sections. To enhance the refining process reliability, an experimental setup was established to investigate the water injection removal of ammonium chloride particle deposits in air cooler tube bundles. Results show that water injection effectively removes ammonium chloride particles. Particle size has a minor influence, whereas inlet velocity, temperature, and water injection rate significantly affect removal efficiency. Increasing inlet velocity from 2 to 5 m/s, temperature from 80 to 110 °C, and water injection rate all enhance removal efficiency. Furthermore, differences between two-row tubes were also observed: the second-row tube exhibits a higher removal ratio due to liquid film formation, which increases Reynolds number and shear force, thereby enhancing dissolution. These findings provide experimental support for optimizing water injection strategies to mitigate corrosion, improving hydrotreatment unit reliability and safety, ensuring the continuous operation of the petroleum and fuel processing industry.

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