Direct Synthesis of Fluorinated Polycyclic Aromatic Dioxanes: Mesomorphism, Luminescence, and Charge Transport

Le résumé fourni par la source

We report a straightforward synthesis of new Janus-fluorinated dioxa-bridged tetracene and pentacene liquid crystals. These materials self-assemble into stable columnar mesophases driven by noncovalent perfluoroarene–arene interactions that promote effective intermolecular π-stacking. The degree of fluorination on the aromatic core plays a pivotal role in the induction of mesomorphism: substitution with two fluorine atoms is insufficient to induce mesomorphism, whereas homologous derivatives bearing four or six fluorine atoms readily self-organize into mesophases. They display luminescence with an absolute quantum yield of 4% in the thin film. These molecules also exhibit an electron mobility rate in the 10 –2 -10 –3 cm 2 V –1 s –1 range, well within the values needed for molecular-based devices. The synthetic strategy described here presents great potential for the construction of novel fluorine-containing molecular materials of interest for applications in organic electronics.

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