A Global Perspective on River Alkalinity: Drivers and Implications for Coastal Ocean Carbonate Chemistry

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Abstract The chemical nature of river water significantly influences the coastal carbonate system, contributing to coastal acidification and creating suboptimal conditions for marine calcifiers. While several regional efforts have assessed observationally based riverine concentrations and fluxes of total alkalinity (TA) and dissolved inorganic carbon (DIC), these values in global ocean biogeochemical models have generally been simplified, often set to zero or balanced against global sediment calcium carbonate burial. To enhance our understanding of rivers' role in the coastal carbonate system, we applied multiple linear regression (MLR) to develop global empirical relationships for estimating river TA and DIC from watershed properties. We find that river TA values are primarily controlled by forest, carbonate rock coverage, and annual mean precipitation, explaining 74% of the spatial variability in TA. The variability explained improves to 77% with the inclusion of permafrost and glacial coverage, especially in high latitude and altitude regions. Additionally, nearly 30% of the spatial variability in the river DIC‐to‐TA ratio can be explained by terrestrial gross primary production and carbonate rock coverage. Applying these MLR‐derived TA and DIC concentrations to a 1/4° resolution global ocean model reduces the high bias in model estimates of global coastal uptake by 69% (equivalent to 0.11 Pg C yr −1 less uptake) compared to the case with zero river TA and DIC. This study elucidates key drivers of the river carbonate system and underscores the importance of accurately representing riverine inputs to improve predictions of global coastal carbon dynamics and ecosystem responses to environmental changes.

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