g-C3N4 based mixed metal/semiconductor heterojunction nanocomposites towards photocatalytic water splitting for hydrogen production: A review

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Now a days, the developemnt of eco-friendly, economical, and efficient photocatalysts for escalating global energy crisis and environmental degradation underscore the urgent need for sustainable hydrogen production via water splitting. For this, traditional photocatalysts are constrained by their limited light absorption, rapid electron-hole recombination, and stability concerns. The non-metal semiconductor polymeric photocatalyst known as g-C 3 N 4 possesses an acceptable energy band gap (2.7 eV), excellent structure, low toxicity, chemical stability, high thermal resistance, cost-effectiveness, easy synthesis, and the ability to absorb light. However, despite all these excellent properties, g-C 3 N 4 has some alarming drawbacks that limit its performance for photocatalytic H 2 generation via photocatalytic water splitting, these drawbacks include massive recombination of charge carriers, limited visible light absorption, and low surface area. A lot of attempts and/or efforts has been made to address these drawbacks for better performance of g-C 3 N 4 –based composites. However, despite all these attempts, there is still little review papers that discuss more on the recent synthesis method and strategies to enhance the performance of g-C 3 N 4 –based photocatalyst for hydrogen production. In this review, we explore the photocatalytic water splitting for hydrogen production using g-C 3 N 4 based mixed metal-semiconductor heterojunction nanocomposites under light irradiation. The study also goes further to discuss more on the structure and properties of g-C 3 N 4 , recent synthesis methods, coupled with metal, semiconductors to form heterojunctions, and elemental doping, as well as photocatalytic performance of H 2 generation of g-C 3 N 4 based heterojunction nanocomposites. Moreover, we outlook the challenges and future directions of g-C 3 N 4 -based photocatalysts, which also provides a reference for the design of other g-C 3 N 4 based catalysts.

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