Red Phosphorus‐Induced Transformation of Gold Mesh into Crystalline Gold Phosphide Mesh

Résumé fourni par la source

Among transition metal phosphides, gold phosphide (Au 2 P 3 ) is particularly uncommon and lacks established synthesis methods for large‐scale or structurally controlled materials, thus hindering its functional applications. This study introduces a synthetic strategy involving annealing gold mesh in red phosphorus vapor within a sealed quartz tube reactor, enabling a direct structural transformation into crystalline Au 2 P 3 while preserving macroscopic geometry. Comprehensive characterization using X‐ray diffraction, scanning electron microscopy, energy‐dispersive X‐ray spectroscopy, and X‐ray photoelectron spectroscopy confirms successful formation, revealing covalent AuP bonding and a semiconducting nature validated by density functional theory simulations, which accurately predict lattice parameters and electronic properties. This method opens possibilities for practical applications of Au 2 P 3 .

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