Research on the Thermodynamic Simulation Model of Antimony–Lead Synergistic Side-Blown Oxidation Smelting Process Based on MetCal

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On the basis of the theory of polyphase equilibrium and the utilization of the MetCal software platform (MetCal v7.81), we adopted the chemical equilibrium constant method and successfully constructed a multiphase equilibrium model and simulation system for the antimony–lead synergistic side-blown oxidation smelting process. In typical production conditions, which encompass factors such as the composition of raw material, the ratio of oxygen to material, and oxygen-enriched concentration, the equilibrium product composition and pivotal technical indices are modeled and computed. Calculation results indicated that, other than the trace elements in the smelting slag, the relative errors of the calculated values for the content of major elements in the antimony-rich crude lead and smelting slag were less than 10% of the measured value after average treatment in production. Therefore, our results showed that the developed model and system preferably embodied the practical production condition of the antimony–lead synergistic side-blown oxidation smelting process, which is capable of precisely forecasting the smelting outcomes and optimizing the process parameters, thereby offering effective guidance for the practical execution of the antimony–lead synergistic side-blown oxidation smelting process.

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