Impact of calcium and pH on ISG alteration at basic pH: Mechanism of formation and transport properties of the gel layer

Le résumé fourni par la source

The dissolution of International Simple Glass (ISG) was investigated at 90 °C, elevated concentration of dissolved silica and in the presence of calcium, with a specific emphasis on basic pH conditions. The leaching solution was labelled with 29 Si, 18 O and 44 Ca in part of the experiments to elucidate the dissolution mechanisms. Based on the isotopic signatures of the gel layer analyzed using Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS), it was concluded that oxygen atoms mostly originate from the solution for all investigated conditions, while silicon atoms almost exclusively originate from the glass. A negative correlation was found between the initial concentration of calcium in solution and the gel layer thickness, suggesting either the formation of a passivating (Si, Ca)-rich layer, a catalytic effect of Ca on the gel densification or a combination of both. In addition, the pH-dependence of the diffusion coefficient of B within the gel was found to be stronger in the basic pH range than in the acidic pH range, which was suggested to originate from the change in coordination of B species at pH 90 ° C ∼ 8.5. Overall, these results suggest that in a (Ca, Si)-rich solution at basic pH, the durability of ISG is stronger than previously thought, as the diffusion coefficient of B under such conditions are lower than expected based on literature.

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