Structure and bonding in molecular salts of opto-electroactive bis(dithiooxalato)metalate complexes: a systematic structural correlations study

Résumé fourni par la source

The search for appropriate structural correlations in molecule-based crystalline salts is of paramount importance to obtain new advanced multifuctional materials with higher performance in nanoscience and nanotechnology. In this article, we focus on the structural features and bonding interactions in the related family of optical- and electroactive molecular salts of anionic mononuclear bis(dithiooxalato)nickel(II), palladium(II), platinum(II), copper(II), copper(III), and zinc(II) complexes with several uni- and divalent, either inorganic or organic countercations. Steric and/or electronic effects of the metal ion and the inorganic or organic countercation determine the molecular structure and conformation of the resulting bis(dithiooxalato)metalate complex anion in the solid state, concerning both the metal coordination environment and the ligand skeleton, twisting and folding along this family of molecular salts.

Ce résumé expose les affirmations des auteurs. BNTIC ne l’interprète pas comme une validation indépendante des résultats.