Detecting underscreening and generalized Kirkwood transitions in aqueous electrolytes

Le résumé fourni par la source

We establish the connection between the measured small angle x-ray scattering signal and the charge-charge correlations underlying Kirkwood transitions (KTs) in 1:1, 2:1, and 3:1 aqueous electrolytes. These measurements allow us to obtain underscreening lengths for bulk electrolytes independently verified by theory and simulations. Furthermore, we generalize the concept of KTs beyond those theoretically predicted for 1:1 electrolytes, which involves the inverse screening length, a0, and the inverse periodicity length, Q0. Above the KTs, we find a universal scaling of a0∝c-ζ/3 and Q0 ∝ c1/3 for the studied electrolyte solutions, where ζ is the ionic strength factor.

Ce résumé expose les affirmations des auteurs. BNTIC ne l’interprète pas comme une validation indépendante des résultats.