Effect of Fluorocarbon Surfactant on Electroforming of Copper Nano-Powders

Le résumé fourni par la source

The electrodeposition behavior, morphology, and particle size of copper nano-powders prepared using fluorocarbon surfactants or fluorocarbon combined with non-ionic compound surfactants were characterized by linear sweep voltammetry, cyclic voltammetry, X-ray diffraction, and field emission scanning electron microscopy. Copper nano-powders prepared using fluorocarbon surfactant or fluorocarbon, non-ionic compound surfactants without added sulfuric acid did not adhere to the plate. The fine particle size of the copper powders, which was mainly influenced by the anionic fluorocarbon surfactant, ranged from 50 to 200 nm. The powder morphology mainly depended on the non-ionic surfactant, and the electrodeposition process was governed by diffusion. The cyclic voltammetry curve indicated that the cathode peak current density is inversely proportional to the plate surface coverage. The change of current density in the electrodeposition process was directly related to the current efficiency. The mechanism of the formation of copper nano-powders by microemulsion electrodeposition was established and explained.

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