Methacrylic Stereoblock Copolymers via the Combination of Catalytic Chain Transfer and Anionic Polymerization

Résumé fourni par la source

A novel synthetic pathway toward stereoblock copolymers by combining catalytic chain transfer polymerization with anionic polymerization is described. Catalytic chain transfer polymerization (CCTP) has been used to synthesize vinyl-terminated polymers, which, after the Michael addition of α-lithioisopropyl isobutyrate, were used as macroinitiators for the anionic polymerization of methacrylate-type monomers. The resultant polymer consists of a predominantly atactic block (originating from the free radical polymerization) and a more isotactoid or syndiotactoid block (originating from the anionic polymerization).

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