Catalytically Active, Coulombic Metal–Organic Frameworks Assembled from Zirconium Metal–Organic Cages and Polyoxometalates
Haofan Yang, Ruilin Han, Filip Formalik, Jingyi Sui et autres
Electrostatical assembly of molecular salts from appropriately designed building blocks offers an attractive route to porous crystalline materials. However, achieving permanent porosity is challenging because Coulombic interactions between charged molecules are typically weaker and far less directional than coordination bonding atom, making …
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