Mechanistic Insights into Photo-Induced Bond Dissociation of A NPIM Derivative: A Case Study on Quantum Spin-Manipulation for Efficient Uncaging
Kenta Kuroishi, Ryuei Hayashi, Ryoko Oyama, S Shinichi TANAKA et autres
Photolabile protecting groups (PPGs) are indispensable tools for spatiotemporally controlled release of reactive functional groups. Recently, we proposed a quantum spin-manipulation (QSM-1) strategy that employs triplet ground-state cations to render ion-pair recombination spin-forbidden, thereby enhancing the uncaging quantum yield. In this study, …
jp, cz (code pays fourni par la source)
0 citations
ChemRxiv