2023
article
OpenAlex
Kelton G. Forson, Rachel N. Owens, Jacob A. Parkman, Benjamin O. Bohman et autres
We report that a 2-phosphinoimidazole-scaffolded bimetallic Rh(II) complex enables the addition of trifluoroacetic acid across an allene under conditions where monometallic Rh(I) or bimetallic Rh(II) tetracarboxylate catalysts fail. The resulting allyl trifluoroacetate products are isolated in good yield across a range of …
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2022
retraction
OpenAlex
Kelton G. Forson, Benjamin O. Bohman, Coriantumr Z. Wayment, Rachel N. Owens et autres
ADVERTISEMENT RETURN TO ISSUEPREVRetractionNEXTORIGINAL ARTICLEThis notice is a retraction.Retraction of “Medium and Large N-Heterocycle Formation via Allene Hydroamination with a Bimetallic Rh(II) Catalyst”Kelton G. ForsonKelton G. ForsonMore by Kelton G. Forson, Benjamin O. BohmanBenjamin O. BohmanMore by Benjamin O. Bohman, Coriantumr Z. …
Accès ouvert
2021
dataset
OpenAlex
Kelton G. Forson, Benjamin O. Bohman, Coriantumr Z. Wayment, Rachel N. Owens et autres
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, …
Accès ouvert
2021
dataset
OpenAlex
Kelton G. Forson, Benjamin O. Bohman, Coriantumr Z. Wayment, Rachel N. Owens et autres
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, …
2021
article
OpenAlex
Kelton G. Forson, Benjamin O. Bohman, Coriantumr Z. Wayment, Rachel N. Owens et autres
We report the synthesis of a 2-phosphinoimidazole-derived bimetallic Rh(II) complex that enables intramolecular allene hydroamination to form 7- to 10-member rings in high yield. Monometallic Rh complexes, in contrast, fail to achieve any product formation. We demonstrate a broad substrate scope for …
us
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Accès ouvert
2021
preprint
OpenAlex
Kelton G. Forson, Benjamin O. Bohman, Coriantumr Z. Wayment, Rachel N. Owens et autres
We report the synthesis of a bimetallic Rh(I) complex containing a bridging CO ligand that facilitates Rh–Rh bond formation. This bimetallic complex enables intramolecular allene hydroamination to form seven to ten-member rings in high yield. Monometallic Rh complexes, in contrast, fail to …
us
(code pays fourni par la source)
Accès ouvert
2021
preprint
OpenAlex
Kelton G. Forson, Benjamin O. Bohman, Coriantumr Z. Wayment, Rachel N. Owens et autres
We report the synthesis of a bimetallic Rh(I) complex containing a bridging CO ligand that facilitates Rh–Rh bond formation. This bimetallic complex enables intramolecular allene hydroamination to form seven to ten-member rings in high yield. Monometallic Rh complexes, in contrast, fail to …
us
(code pays fourni par la source)
Accès ouvert
2021
preprint
OpenAlex
Kelton G. Forson, Benjamin O. Bohman, Coriantumr Z. Wayment, Rachel N. Owens et autres
We report the synthesis of a bimetallic Rh(I) complex containing a bridging CO ligand that facilitates Rh–Rh bond formation. This bimetallic complex enables intramolecular allene hydroamination to form seven to ten-member rings in high yield. Monometallic Rh complexes, in contrast, fail to …
us
(code pays fourni par la source)
Accès ouvert
2021
preprint
OpenAlex
Kelton G. Forson, Benjamin O. Bohman, Coriantumr Z. Wayment, Rachel N. Owens et autres
We report the synthesis of a bimetallic Rh(I) complex containing a bridging CO ligand that facilitates Rh–Rh bond formation. This bimetallic complex enables intramolecular allene hydroamination to form seven to ten-member rings in high yield. Monometallic Rh complexes, in contrast, fail to …
us
(code pays fourni par la source)